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This document specifies a method for the determination of the mass fractions of the elements Al (aluminium), As (arsenic), Ba (barium), Be (beryllium), Ca (calcium), Cd (cadmium), Co (cobalt), Cr (chromium), Cu (copper), Fe (iron), In (indium), K (potassium), Li (lithium), Mg (magnesia), Mn (manganese), Mo (molybdenum), Na (sodium), Ni (nickel), Pb (lead), Sb (antimony), Sr (strontium), Ti (titanium), V (vanadium), Zn (zinc) and Zr (zirconium) in the trace range on the surface of a silicon wafer, using mass spectrometry with inductively coupled plasma (ICP-MS) as method of determination. The method is valid for mass fractions of trace elements between 10 ng/kg up to 10 000 ng/kg (m/m) in the scanning solution. This document is only valid for silicon wafers the surface of which consists of a layer decomposable by hydrogen fluoride. This document has been prepared by Working Committee NA 062-02-21 AA "Prüfung von Prozesschemikalien für die Halbleitertechnologie" ("Testing of process materials for semiconductor technology") at the Materials Testing Standards Committee (NMP) at DIN.